|
|
malonyl-CoA + ricinoleoyl-CoA + H+ <=> 3-oxo-lesqueroloyl-CoA + CoA + CO2
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
MetaCyc:
RXN-14492
|
|
|
|
oleoyl-CoA + glycerolipid <=> an_oleoyl-[glycerolipid] + CoA
|
2.3.1.23
1-acylglycerophosphocholine O-acyltransferase
|
–
|
|
MetaCyc:
RXN-9670
|
|
|
|
[glycerolipid]-(11Z)-eicosenoate + ferricytochrome_b5 + O2 + H+ <=> [glycerolipid]-lesquerolate + ferricytochrome_b5 + H2O
|
1.14.18.4
phosphatidylcholine 12-monooxygenase
|
–
|
|
MetaCyc:
RXN-14488
|
|
|
|
(3R)-hydroxy-auricoloyl-CoA <=> (2E,11Z,17Z)-14R-hydroxy-icosa-11,17-trienoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
MetaCyc:
RXN-16155
|
|
|
|
(2E,11Z)-icosa-2,11-dienoyl-CoA + NADPH + H+ <=> eicosenoyl-CoA + NADP+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-14486
|
|
|
|
auricoloyl-CoA + NADP+ <=> (2E,11Z,17Z)-14R-hydroxy-icosa-11,17-trienoyl-CoA + NADPH + H+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-16156
|
|
|
|
malonyl-CoA + oleoyl-CoA + H+ <=> 3-oxo-eicosenoyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
MetaCyc:
RXN-13322
|
|
|
|
3R-hydroxy-(11Z)-eicos-11-enoyl-CoA + NADP+ <=> 3-oxo-eicosenoyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-14484
|
|
|
|
3R-hydroxy-(11Z)-eicos-11-enoyl-CoA <=> (2E,11Z)-icosa-2,11-dienoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
MetaCyc:
RXN-14485
|
|
|
|
densipoloyl-CoA + glycerolipid <=> [glycerolipid]-densipolate + CoA
|
2.3.1.23
1-acylglycerophosphocholine O-acyltransferase
|
–
|
|
MetaCyc:
RXN-16150
|
|
|
|
eicosenoyl-CoA + glycerolipid <=> [glycerolipid]-(11Z)-eicosenoate + CoA
|
2.3.1.23
1-acylglycerophosphocholine O-acyltransferase
|
–
|
|
MetaCyc:
RXN-16158
|
|
|
|
ricinoleoyl-CoA + glycerolipid <=> [glycerolipid]-ricinoleate + CoA
|
2.3.1.23
1-acylglycerophosphocholine O-acyltransferase
|
–
|
|
MetaCyc:
RXN-16151
|
|
|
|
3R-hydroxy-lesqueroloyl-CoA <=> trans-lesqueroloyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
MetaCyc:
RXN-14494
|
|
|
|
[glycerolipid]-ricinoleate + O2 + ferricytochrome_b5 + H+ <=> [glycerolipid]-densipolate + H2O + ferricytochrome_b5
|
1.14.19.25
acyl-lipid omega-3 desaturase (cytochrome b5)
|
–
|
|
MetaCyc:
RXN-16149
|
|
|
|
auricoloyl-CoA + glycerolipid <=> [glycerolipid]-auricolate + CoA
|
2.3.1.23
1-acylglycerophosphocholine O-acyltransferase
|
–
|
|
MetaCyc:
RXN-16157
|
|
|
|
lesqueroloyl-CoA + glycerolipid <=> [glycerolipid]-lesquerolate + CoA
|
2.3.1.23
1-acylglycerophosphocholine O-acyltransferase
|
–
|
|
MetaCyc:
RXN-16152
|
|
|
|
[glycerolipid]-lesquerolate + O2 + ferricytochrome_b5 + H+ <=> [glycerolipid]-auricolate + H2O + ferricytochrome_b5
|
1.14.19.25
acyl-lipid omega-3 desaturase (cytochrome b5)
|
–
|
|
MetaCyc:
RXN-14491
|
|
|
|
malonyl-CoA + densipoloyl-CoA + H+ <=> 3-oxoauricoloyl-CoA + CoA + CO2
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
MetaCyc:
RXN-16153
|
|
|
|
(3R)-hydroxy-auricoloyl-CoA + NADP+ <=> 3-oxoauricoloyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-16154
|
|
|
|
3R-hydroxy-lesqueroloyl-CoA + NADP+ <=> 3-oxo-lesqueroloyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-14493
|
|
|
|
trans-lesqueroloyl-CoA + NADPH + H+ <=> lesqueroloyl-CoA + NADP+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-14495
|
|
|
|
an_oleoyl-[glycerolipid] + O2 + ferricytochrome_b5 + H+ <=> [glycerolipid]-ricinoleate + H2O + ferricytochrome_b5
|
1.14.18.4
phosphatidylcholine 12-monooxygenase
|
–
|
|
MetaCyc:
RXN-16148
|
|